Unconventional Oil
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Unconventional oil is
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
produced or extracted using techniques other than the conventional method (
oil well An oil well is a drillhole boring in Earth that is designed to bring petroleum oil hydrocarbons to the surface. Usually some natural gas is released as associated petroleum gas along with the oil. A well that is designed to produce only gas may ...
). Industry and governments across the globe are investing in unconventional oil sources due to the increasing scarcity of conventional
oil reserves An oil is any polarity (chemistry), nonpolar chemical substance that is composed primarily of Hydrocarbon, hydrocarbons and is hydrophobe, hydrophobic (does not mix with water) & lipophilicity, lipophilic (mixes with other oils). Oils are usu ...
. Unconventional oil and gas have already made a dent in international energy linkages by reducing US energy import dependency.


Sources

According to the
International Energy Agency The International Energy Agency (IEA) is a Paris-based autonomous intergovernmental organisation, established in 1974, that provides policy recommendations, analysis and data on the entire global energy sector, with a recent focus on curbing carb ...
's (IEA) ''
World Energy Outlook The annual ''World Energy Outlook'' is the International Energy Agency's flagship publication, widely recognised as the most authoritative source for global energy projections and analysis. It represents the leading source for medium to long-term ...
2001'' unconventional oil included " oil shales,
oil sands Oil sands, tar sands, crude bitumen, or bituminous sands, are a type of unconventional petroleum deposit. Oil sands are either loose sands or partially consolidated sandstone containing a naturally occurring mixture of sand, clay, and wate ...
-based synthetic crudes and derivative products, ( heavy oil, Orimulsion®), coal-based liquid supplies, biomass-based liquid supplies,
gas to liquid Gas to liquids (GTL) is a refinery process to convert natural gas or other gaseous hydrocarbons into longer-chain hydrocarbons, such as gasoline or diesel fuel. Methane-rich gases are converted into liquid synthetic fuels. Two general strategies ex ...
(GTL) - liquids arising from chemical processing of gas." In the IEA's ''World Energy Outlook 2011'' report, " conventional oil include extra-heavy oil, natural bitumen (oil sands), kerogen oil, liquids and gases arising from chemical processing of natural gas (GTL), coal-to-liquids (CTL) and additives."


Definition

In their 2013 webpage jointly published with the
Organisation for Economic Co-operation and Development The Organisation for Economic Co-operation and Development (OECD; french: Organisation de coopération et de développement économiques, ''OCDE'') is an intergovernmental organization, intergovernmental organisation with 38 member countries ...
(OECD), the IEA observed that as technologies and economies change, definitions for unconventional and conventional oils also change. According to the US Department of Energy (DOE), "unconventional oils have yet to be strictly defined." In a communication to the UK entitled ''Oil Sands Crude'' in the series ''The Global Range of Crude Oils'', it was argued that commonly used definitions of unconventional oil based on production techniques are imprecise and time-dependent. They noted that the International Energy Agency does not recognize any universally accepted definition for "conventional" or "unconventional" oil. Extraction techniques that are categorized as "conventional" use "unconventional means" such as gas re-injection or the use of heat" not traditional oil extraction methods. As the use of newer technologies increase, "unconventional" oil recovery has become the norm not the exception. They noted that the Canadian oil sands production "pre-dates oil production from areas such as the North Sea (the source of a benchmark crude oil known as "Brent"). Under revised definitions, petroleum ''products'', such as
Western Canadian Select Western Canadian Select (WCS) is a heavy sour blend of crude oil that is one of North America's largest heavy crude oil streams and, historically, its cheapest. It was established in December 2004 as a new heavy oil stream by EnCana (now Ceno ...
, a heavy crude benchmark blend produced in
Hardisty, Alberta Hardisty is a town in Flagstaff County in east-central Alberta, Canada. It is approximately from the Saskatchewan border, near the crossroads of Highway 13 and Highway 881, in the Battle River Valley. Hardisty is mainly known as a pivotal pet ...
may migrate from its categorization as unconventional oil to conventional oil because of its density, even though the oil sands are an unconventional resource.


Oil sands

Oil sands generally consist of extra heavy crude oil or crude
bitumen Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
trapped in unconsolidated sandstone. These hydrocarbons are forms of
crude oil Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
that are extremely dense and viscous, with a consistency ranging from that of
molasses Molasses () is a viscous substance resulting from refining sugarcane or sugar beets into sugar. Molasses varies in the amount of sugar, method of extraction and age of the plant. Sugarcane molasses is primarily used to sweeten and flavour foods ...
for some extra-heavy oil to as solid as peanut butter for some bitumen at room temperature, making extraction difficult. These heavy crude oils have a density (specific gravity) approaching or even exceeding that of water. As a result of their high viscosity, they cannot be produced by conventional methods, transported without heating or dilution with lighter hydrocarbons, or refined by older oil refineries without major modifications. Such heavy crude oils often contain high concentrations of
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
and heavy metals, particularly nickel and vanadium, which interfere with refining processes, although lighter crude oils can also suffer from sulfur and heavy metal contamination. These properties present significant environmental challenges to the growth of heavy oil production and use. Canada's Athabasca oil sands and Venezuela's Orinoco heavy oil belt are the best known example of this kind of unconventional reserve. In 2003 the estimated reserves were . Heavy oil sands and bituminous sands occur worldwide. The two most important deposits are the Athabasca Oil Sands in
Alberta, Canada Alberta ( ) is one of the thirteen provinces and territories of Canada, provinces and territories of Canada. It is part of Western Canada and is one of the three Canadian Prairies, prairie provinces. Alberta is bordered by British Columbia to t ...
and the Orinoco heavy oil belt in
Venezuela Venezuela (; ), officially the Bolivarian Republic of Venezuela ( es, link=no, República Bolivariana de Venezuela), is a country on the northern coast of South America, consisting of a continental landmass and many islands and islets in th ...
. The hydrocarbon content of these deposits is either crude
bitumen Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
or extra-
heavy crude oil Heavy crude oil (or extra heavy crude oil) is highly-viscous oil that cannot easily flow from production wells under normal reservoir conditions. It is referred to as "heavy" because its density or specific gravity is higher than that of light cru ...
, the former of which is often upgraded to synthetic crude (syncrude) and the latter of which the Venezuelan fuel
Orimulsion Orimulsion is a registered trademark name for a bitumen-based fuel that was developed for industrial use by Intevep, the Research and Development Affiliate of Petroleos de Venezuela SA (PDVSA), following earlier collaboration on oil emulsions with ...
is based. The Venezuelan extra heavy oil deposits differ from the Canadian bituminous sands in that they flow more readily at Venezuela's higher reservoir temperatures and could be produced by conventional techniques, but the recovery rates would be less than the unconventional Canadian techniques (about 8% versus up to 90% for surface mining and 60% for steam assisted gravity drainage). In 2011, Alberta's total proven oil reserves were 170.2 billion barrels representing 11 percent of the total global oil reserves (1,523 billion barrels) and 99% of Canada's oil reserves. By 2011 Alberta was supplying 15% of the United States crude oil imports, exporting about of crude oil. The 2006 projections for 2015, were about . At that rate, the Athabasca oil sands reserves would last less than 160 years. About 80 percent of Alberta's bituminous deposits can be extracted using in-situ methods such as steam assisted gravity drainage and 20 percent by surface mining methods. The Northern Alberta oil sands in Athabasca, Cold Lake and Peace River areas contain an estimated 2 trillion barrels (initial volume in place) of crude bitumen and extra-heavy oil of which 9 percent was considered recoverable using technology available in 2013. It is estimated by oil companies that the Athabasca and Orinoco sites (both of similar size) have as much as two-thirds of total global oil deposits. They have only recently been considered proven reserves of oil. This is because oil prices have risen since 2003 and costs to extract oil from these mines have fallen. Between 2003 and 2008, world oil prices rose to over $140, and costs to extract the oil fell to less than $15 per barrel at the
Suncor Suncor Energy (french: Suncor Énergie) is a Canadian integrated energy company based in Calgary, Alberta. It specializes in production of synthetic crude from oil sands. In the 2020 Forbes Global 2000, Suncor Energy was ranked as the 48th-lar ...
and Syncrude mines. In 2013, crude oil from the Canadian oil sands was expensive oil to produce, although new US
tight oil Tight oil (also known as shale oil, shale-hosted oil or light tight oil, abbreviated LTO) is light crude oil contained in unconventional petroleum-bearing formations of low permeability, often shale or tight sandstone. Economic production from ...
production was similarly expensive. Supply costs for Athabasca oil sands projects were approximately US$50 to US$90 per barrel. However, costs for Bakken, Eagle Ford and Niobrara were higher at approximately US$70 to US$90, according to 135 global oil and gas companies surveyed reported by the
Financial Post The ''Financial Post'' was an English Canadian business newspaper, which published from 1907 to 1998. In 1998, the publication was folded into the new ''National Post'',"Black says Post to merge with new paper". ''The Globe and Mail'', July 23, ...
. Extracting a significant percentage of world oil production from these deposits will be difficult since the extraction process takes a great deal of capital, human power and land. Another constraint is energy for project
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...
and
electricity generation Electricity generation is the process of generating electric power from sources of primary energy. For electric utility, utilities in the electric power industry, it is the stage prior to its Electricity delivery, delivery (Electric power transmi ...
, currently coming from
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
, which in recent years has seen a surge in production and a corresponding drop in price in North America. With the new supply of shale gas in North America, the need for alternatives to natural gas has been greatly diminished. A 2009 study by CERA estimated that production from Canada's oil sands emits "about 5–15% more carbon dioxide, over the "well-to-wheels" lifetime analysis of the fuel, than average crude oil." Author and investigative journalist David Strahan that same year stated that IEA figures show that carbon dioxide emissions from the tar sands are 20% higher than average emissions from oil.


Tight oil

Tight oil, including light tight oil (sometimes confusingly the term 'shale oil' is used instead of 'light tight oil') is crude oil contained in petroleum-bearing formations of low permeability, often
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
or tight sandstone. Economic production from tight oil formations requires the same
hydraulic fracturing Fracking (also known as hydraulic fracturing, hydrofracturing, or hydrofracking) is a well stimulation technique involving the fracturing of bedrock formations by a pressurized liquid. The process involves the high-pressure injection of "frack ...
and often uses the same horizontal well technology used in the production of
shale gas Shale gas is an unconventional natural gas that is found trapped within shale formations. Since the 1990s a combination of horizontal drilling and hydraulic fracturing has made large volumes of shale gas more economical to produce, and some ...
. It should not be confused with
oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitute ...
, which is shale rich in
kerogen Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It ...
, or
shale oil Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil c ...
, which is synthetic oil produced from oil shales. Therefore, the
International Energy Agency The International Energy Agency (IEA) is a Paris-based autonomous intergovernmental organisation, established in 1974, that provides policy recommendations, analysis and data on the entire global energy sector, with a recent focus on curbing carb ...
recommends to use the term "light tight oil" for oil produced from shales or other very low permeability formations, while World Energy Resources 2013 report by the
World Energy Council The World Energy Council is a global forum for thought-leadership and tangible engagement with headquarters in London. Its mission is 'To promote the sustainable supply and use of energy for the greatest benefit of all people'. The idea for the fo ...
uses the term "tight oil".


Oil shale

Oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitute ...
is an organic-rich
fine-grained Granularity (also called graininess), the condition of existing in granules or grains, refers to the extent to which a material or system is composed of distinguishable pieces. It can either refer to the extent to which a larger entity is sub ...
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
containing significant amounts of
kerogen Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It ...
(a solid mixture of organic
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
s) from which technology can extract liquid
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
s (
shale oil Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil c ...
) and combustible
oil shale gas Oil shale gas (also: retort gas or retorting gas) is a synthetic non-condensable gas mixture (syngas) produced by oil shale thermal processing (pyrolysis). Although often referred to as shale gas, it differs from the natural gas produced from shale ...
. The kerogen in oil shale can be converted to shale oil through the chemical processes of
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
,
hydrogenation Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate organ ...
, or
thermal dissolution Thermal dissolution is a method of liquefaction of solid fossil fuels. It is a hydrogen-donor solvent refining process. It may be used for the shale oil extraction and coal liquefaction. Other liquids extraction processes from solid fuels are py ...
. The temperature when perceptible decomposition of oil shale occurs depends on the time-scale of the pyrolysis; in the above ground retorting process the perceptible decomposition occurs at , but proceeds more rapidly and completely at higher temperatures. The rate of decomposition is the highest at a temperature of to . The ratio of shale gas to shale oil depends on the retorting temperature and as a rule increases with the rise of temperature. For the modern '' in-situ'' process, which might take several months of heating, decomposition may be conducted as low as . Depending on the exact properties of oil shale and the exact processing technology, the retorting process may be water and energy extensives. Oil shale has also been burnt directly as a low-grade fuel. A 2016 estimate by the World Energy Council set total world shale oil resources at 6.05 trillion barrels. The
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
is believed to hold more than 80% of that total. There are around 600 known oil shale deposits around the world, including major deposits in the United States. Although oil shale deposits occur in many countries, only 33 countries possess known deposits of possible economic value. The largest deposits in the world occur in the United States in the
Green River Formation The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes in three basins along the present-day Green River in Colorado, Wyoming, and Utah. The sediments are deposited in very fine ...
, which covers portions of
Colorado Colorado (, other variants) is a state in the Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the western edge of t ...
,
Utah Utah ( , ) is a state in the Mountain West subregion of the Western United States. Utah is a landlocked U.S. state bordered to its east by Colorado, to its northeast by Wyoming, to its north by Idaho, to its south by Arizona, and to it ...
, and
Wyoming Wyoming () is a U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the south ...
. Approximately 70% of this resource lies on land owned or managed by the United States federal government. Well-explored deposits, potentially possessing additional economic value, include the
Green River Green River may refer to: Rivers Canada * Green River (British Columbia), a tributary of the Lillooet River *Green River, a tributary of the Saint John River, also known by its French name of Rivière Verte *Green River (Ontario), a tributary of ...
deposits in the western United States, the Tertiary deposits in
Queensland ) , nickname = Sunshine State , image_map = Queensland in Australia.svg , map_caption = Location of Queensland in Australia , subdivision_type = Country , subdivision_name = Australia , established_title = Before federation , established_ ...
, Australia, deposits in
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
and
Estonia Estonia, formally the Republic of Estonia, is a country by the Baltic Sea in Northern Europe. It is bordered to the north by the Gulf of Finland across from Finland, to the west by the sea across from Sweden, to the south by Latvia, a ...
, the El-Lajjun deposit in
Jordan Jordan ( ar, الأردن; tr. ' ), officially the Hashemite Kingdom of Jordan,; tr. ' is a country in Western Asia. It is situated at the crossroads of Asia, Africa, and Europe, within the Levant region, on the East Bank of the Jordan Rive ...
, and deposits in France, Germany,
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
,
Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to ...
, China, southern
Mongolia Mongolia; Mongolian script: , , ; lit. "Mongol Nation" or "State of Mongolia" () is a landlocked country in East Asia, bordered by Russia to the north and China to the south. It covers an area of , with a population of just 3.3 million, ...
and Russia. These deposits have given rise to expectations of yielding at least of shale oil per tonne of shale, using the Fischer Assay method. According to a survey conducted by the
RAND Corporation The RAND Corporation (from the phrase "research and development") is an American nonprofit global policy think tank created in 1948 by Douglas Aircraft Company to offer research and analysis to the United States Armed Forces. It is financed ...
, the cost of producing a barrel of oil at a surface retorting complex in the United States (comprising a mine, retorting plant, upgrading plant, supporting utilities, and spent shale reclamation), would range between
US$ The United States dollar (symbol: $; code: USD; also abbreviated US$ or U.S. Dollar, to distinguish it from other dollar-denominated currencies; referred to as the dollar, U.S. dollar, American dollar, or colloquially buck) is the official ...
70–95 ($440–600/m3, adjusted to 2005 values). , industry uses oil shale for shale oil production in
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
,
China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
and
Estonia Estonia, formally the Republic of Estonia, is a country by the Baltic Sea in Northern Europe. It is bordered to the north by the Gulf of Finland across from Finland, to the west by the sea across from Sweden, to the south by Latvia, a ...
. Several additional countries started assessing their reserves or had built experimental production plants. In the US, if oil shale could be used to meet a quarter of the current demand, of recoverable resources would last for more than 400 years.


Thermal depolymerization

Thermal depolymerization Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalysed or un-catalysed and is distinct from other forms of depolymerisation which may rely o ...
(TDP) has the potential to recover energy from existing sources of waste such as
petroleum coke Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracki ...
as well as pre-existing waste deposits. This process, which imitates those that occur in nature, uses heat and pressure to break down organic and
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
s through a method known as
hydrous pyrolysis In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
. Because energy output varies greatly based on feedstock, it is difficult to estimate potential energy production. According to Changing World Technologies, Inc., this process even has the ability to break down several types of materials, many of which are poisonous to both humans and the environment.


Coal and gas conversion

Using
synthetic fuel Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by refo ...
processes, the conversion of coal and natural gas has the potential to yield great quantities of unconventional oil and/or refined products, albeit at much lower net energy output than the historic average for conventional oil extraction. In its day - prior to the drilling of oilwells to tap reservoirs of crude oil- the
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
of mined solid organic-rich deposits was the conventional method of producing mineral oils. Historically, petroleum was already being produced on an industrial scale in the United Kingdom and the United States by dry distillation of cannel coal or
oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitute ...
in the first half of the 19th Century. Yields of oil from simple pyrolysis, however, are limited by the composition of the material being pyrolysed, and modern 'oil-from-coal' processes aim for a much higher yield of organic liquids, brought about by chemical reaction with the solid feedstuff. The four primary conversion technologies used for the production of unconventional oil and refined products from coal and gas are the indirect conversion processes of the
Fischer–Tropsch process The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatu ...
and the Mobil Process (also known as Methanol to Gasoline), and the direct conversion processes of the
Bergius process The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of high-volatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius ...
and the
Karrick process The Karrick process is a low-temperature carbonization (LTC) and pyrolysis process of carbonaceous materials. Although primarily meant for coal carbonization, it also could be used for processing of oil shale, lignite or any carbonaceous materials ...
.
Sasol Sasol Limited is an integrated energy and chemical company based in Sandton, South Africa. The company was formed in 1950 in Sasolburg, South Africa and built on processes that were first developed by German chemists and engineers in the early ...
has run a coal-to-liquids plant based on Fischer Tropsch conversion in South Africa since the 1970s. Because of the high cost of transporting natural gas, many known but remote fields were not being developed. On-site conversion to liquid fuels are making this energy available under present market conditions. Fischer Tropsch fuels plants converting natural gas to fuel, a process broadly known as
gas-to-liquids Gas to liquids (GTL) is a refinery process to convert natural gas or other gaseous hydrocarbons into longer-chain hydrocarbons, such as gasoline or diesel fuel. Methane-rich gases are converted into liquid synthetic fuels. Two general strategies ex ...
are operating in Malaysia, South Africa, and Qatar. Large direct conversion coal to liquids plants are currently under construction, or undergoing start-up in China. Total global
synthetic fuel Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by refo ...
production capacity exceeds , and is expected to grow rapidly in coming years, with multiple new plants currently under construction.


Known adverse health effects

Unconventional oil drilling, like
unconventional gas Unconventional gas is natural gas obtained from sources of production that are, in a given era and location, considered to be new and different when compared with conventional gas. Sources that are at times considered to be unconventional include ...
drilling, has degraded air quality, contaminated
groundwater Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
, and increased
noise pollution Noise pollution, also known as environmental noise or sound pollution, is the propagation of noise with ranging impacts on the activity of human or animal life, most of them are harmful to a degree. The source of outdoor noise worldwide is main ...
. Such drilling has also been found to correlate with poor
fetal growth Prenatal development () includes the development of the embryo and of the fetus during a viviparous animal's gestation. Prenatal development starts with fertilization, in the germinal stage of embryonic development, and continues in fetal deve ...
and a higher
preterm birth Preterm birth, also known as premature birth, is the Childbirth, birth of a baby at fewer than 37 weeks Gestational age (obstetrics), gestational age, as opposed to full-term delivery at approximately 40 weeks. Extreme preterm is less than 28 we ...
rate for residents who live near drilling sites.
Gas flaring A gas flare, alternatively known as a flare stack, flare boom, ground flare, or flare pit is a gas combustion device used in places such as petroleum refineries, chemical plants and natural gas processing plants, oil or gas extraction sites hav ...
, which is a common industry practice, releases a toxic mix of harmful chemicals, including
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, ...
,
particulates Particulates – also known as atmospheric aerosol particles, atmospheric particulate matter, particulate matter (PM) or suspended particulate matter (SPM) – are microscopic particles of solid or liquid matter suspended in the air. The ter ...
,
nitrogen oxide Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or n ...
s,
heavy metals upright=1.2, Crystals of osmium, a heavy metal nearly twice as dense as lead">lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead Heavy metals are generally defined as ...
,
black carbon Chemically, black carbon (BC) is a component of fine particulate matter (PM ≤ 2.5 µm in aerodynamic diameter). Black carbon consists of pure carbon in several linked forms. It is formed through the incomplete combustion of fossil fuel ...
,
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
,
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
and other
volatile organic compounds Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature Colloquially, "room temperature" is a range of air temperatures that most people prefer for indoor settings. It feels comfortable to a ...
,
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
and other
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
compounds, which are known to exacerbate
asthma Asthma is a long-term inflammatory disease of the airways of the lungs. It is characterized by variable and recurring symptoms, reversible airflow obstruction, and easily triggered bronchospasms. Symptoms include episodes of wheezing, cou ...
and other respiratory disease. Just three areas together are responsible for 83% of known unconventional oil extraction site flares, unconventional gas extraction site flares and fracking flares in the contiguous United States, and approximately a half million Americans, disproportionately African-Americans, Indigenous peoples of the Americas, Native Americans, and other people of color, live within five kilometers of these three areas.


Environmental concerns

As with all forms of mining, there are hazardous tailings and waste generated from the varied processes of oil extraction and production. Environmental concerns with heavy oils are similar to those with lighter oils. However, they provide additional concerns, such as the need to heat heavy oils to pump them out of the ground. Extraction also requires large volumes of water. The environmental impacts of oil shale differ depending on the type of extraction; however, there are some common trends. The mining process releases carbon dioxide, in addition to other oxides and pollutants, as the shale is heated. Furthermore, there is some concern about some of the chemicals mixing with ground water (either as Surface runoff, runoff or through seeping). There are processes either in use or under development to help mitigate some of these environmental concerns. The conversion of coal or natural gas into oil generates large amounts of carbon dioxide in addition to all the impacts of gaining these resources to begin with. However, placing plants in key areas can reduce the effective emissions due to pumping the carbon dioxide into oil beds or coal beds to enhance the recovery of oil and methane. Carbon dioxide is a greenhouse gas, so the increased carbon dioxide produced from both the more involved extraction process with unconventional oil, as well as burning the oil itself, has led to deep concerns about unconventional oil worsening the impacts of climate change.


Economics

Sources of unconventional oil will be increasingly relied upon when conventional oil becomes more expensive due to Hubbert peak, depletion. Conventional oil sources are currently preferred because they are less expensive than unconventional sources. New technologies, such as Steam injection (oil industry), steam injection for oil sands deposits, are being developed to reduce unconventional oil production costs. In May 2013 the IEA in its ''Medium-Term Oil Market Report'' (MTOMR) said that the North American oil production surge led by unconventional oils - US light,
tight oil Tight oil (also known as shale oil, shale-hosted oil or light tight oil, abbreviated LTO) is light crude oil contained in unconventional petroleum-bearing formations of low permeability, often shale or tight sandstone. Economic production from ...
(LTO) and Canadian oil sands - had produced a global supply shock that would reshape the way oil is transported, stored, refined and marketed.


See also

*Unconventional (oil & gas) reservoir *Extreme energy *Renewable energy *Future energy development *Hubbert peak *Energy development *Alternative fuels *
Fischer–Tropsch process The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatu ...
*Synthetic Liquid Fuels Program *World energy resources and consumption *Oil Megaprojects *Unconventional wind turbines *Unconventional gas


Notes


References

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Further reading

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External links


Unconventional ResourcesCentre For EnergyWorld CTL
{{Petroleum industry Unconventional oil, Peak oil Petroleum production Synthetic fuels